【重金求助!!!电化学沉积氧化石墨烯复合硅烷的审稿意见该如何回答啊】
【重金求助!!!电化学沉积氧化石墨烯复合硅烷的审稿意见该如何回答啊】。某个期刊,大修,不知道该如何详细的正确回答,重金求助高手帮忙解释回答!!!
如果您回复的很有价值,本人承诺,金币可以一次性奉上!!!
该审稿意见如下:
I have one observation that GO remains the suspended particle in the ceramic Si-O-Si matrix. It is very hard to understand that GO has only physical dispersion in polymerization. While polymerization was performed in presents of GO by electrochemical input. Even if GO has been reduced to some extend by electrochemically; still there are maximum chances of formation of Si-O-GO co-ordination. It has only physical dispersion no covalent connectivity towards the polymeric matrix. Rather GO is active molecules could be integrated with Si-O-GO kind of composite. It may provide sigma as well as pi-pi co-ordination towards the surface for good adhesion and ultimately good corrosion resistivity. Please provide the rational justification to above discussion.
The ratio of the G band intensity (IG) to the D band intensity (ID) was about 0.47. 0.47 is for which sample (not clearly mentioned in text). Only reductions of GO increase the ID /IG ration justify this with reference. Why not it may be covalent bonding of GO and DTES affect the ID /IG ration (Please go to the reference RSC Adv., 2014, 4, 49264-49272). In IR 1630 cm-1 (C=O stretching vibrations) was not significantly observed in GO/DTES if GO is present in significant amount. IR values are randomly mentioned stretching and bending not specifically mention mode of vibration of which bond C-C or C-Si or C-H or Si-O.
非常感谢
[ Last edited by hustczy on 2017-1-14 at 23:04 ]
===有问必答===
这些英语怎么这么乱七八糟的,太难以理解清楚!“It is very hard to understand that GO has only physical dispersion in polymerization. ”和“ It has only physical dispersion no covalent connectivity towards the polymeric matrix.”这两句话不是相反的意思的吗?
我的理解是;
上一段的大概的意思是要楼主解释“Si-O-GO“的存在性,有没有存在这些结合的最挂状态。
以我判断,第二段里审稿人的意思是ID/IG的变化不能完全反映着氧化石墨烯的还原,也就是说ID/IG的下降也可能跟氧化石墨烯和DTES之间的共价键有关。还有红外光谱里没有明显的出现GO/DTES 的,而且没有说明C-C、 C-Si、C-H和Si-O的存在。
就这样,加油!
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请问您知道复合电镀Ni-P-SiC时怎么让碳化硅悬浮在电镀液中吗???拜托啦,谢谢
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